Title

Solution properties of nickel(II) tetra(4-N-methylpyridyl) porphine and the influence of acetone, pyridine and imidazole

Document Type

Article

Publication Date

1-1-1974

Abstract

NiTMPyP has been shown to exist in aqueous solution as an equilibrium mixture between diamagnetic, four-coordinate nickel and paramagnetic, six-coordinate nickel complexed by water molecules in the axial positions. The addition of acetone promotes the four-coordinate species while the addition of pyridine or imidazole promotes the formation of six-coordinate species which may contain no, one or two molecules of the nitrogenous base depending on the ligand concentration. © 1974.

Publication Name

Journal of Inorganic and Nuclear Chemistry

Volume Number

36

First Page

599

Last Page

606

Issue Number

3

DOI

10.1016/0022-1902(74)80120-X

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