Title

Lewis Acid-Base Interactions of Zinc αβ,γ,δ-Tetraphenylporphine with Several Neutral Donors

Document Type

Article

Publication Date

4-1-1973

Abstract

The thermodynamic parameters for the formation of a 1:1 adduct between zinc αβ,γ,δ-tetraphenylporphine and several neutral Lewis bases are reported. For the bases studied, the enthalpies of adduct formation increase in the order S < O < P < N. The effect of change in extinction coefficient of the adduct on the determination of the equilibrium constant is discussed in terms of the Rose-Drago equation. © 1973, American Chemical Society. All rights reserved.

Publication Name

Inorganic Chemistry

Volume Number

12

First Page

936

Last Page

939

Issue Number

4

DOI

10.1021/ic50122a048

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